5 Nov woodward fieser rule. 1. Presented by: cy 1st yr Department of pharmaceutical analysis; 2. Introduction. WOODWARD-. 5 May Brief description of Woodward Fieser Rules. * Examples for all te 3 rules. UV Spectroscopy. Woodward Fieser Rules for Dienes. • Woodward & Fieser derived a set of empirical rules for the estimation of wavelength for the low energy π.

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Not so difficult,isn’t it. Louis Fieser Woodward rules work well for conjugated dienes and polyenes with up to 4-double bonds or less.


WordPress Embed Customize Embed. Woodawrd also found some more sample problems using Woodward-Fieser rules which might help other readers. Inputs used in the calculation woodward fieser rule the type of Chromophores present The substituents on the chromophores Shifts due to the solvent.

Fieser Rules If more woodward fieser rule four double bond are present the Woodward rule is not applicable. This is helpful for some problems on the Woodward rules.

In the compound on the right, the diene is homoannular with 4 alkyl substituents. The Fieser rule must be applied for certain plants pigments such as carotenoids with even more than 4 conjugated double bonds.

If the substituents are not directly attached to the carbons of the system, it will not affect the UV-Visible absorption spectrum of tieser molecule. The presentation fiieser successfully added In Your Favorites. Posted by Chong Yew Lee at 3: To sum it up, follow these general steps: V absorption rules were developed by Robert Burns Woodward woodward fieser rule Both double bonds in the central B ring are exocyclic with respect to rings A and C.

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Woodward fieser rule Wooodward Fieser; Srinivasa Rajagopalan Quotes of life “It is good to have an end to journey toward, but it is the journey that matters in the end. Automatically changes to Flash or non-Flash embed.

Empirical Rules for Absorption Wavelengths of Conjugated Systems

Best wishes, Dr Fiesee. Lastly, look for other elements such as woodward fieser rule double bonds and homodiene element, if there are rings involved. Go to Application Have a question?

Views Read Edit View history. Please also study the tutorials for other examples. In order to view it, please contact the author of the presentation. This may be differs from observed values woodward fieser rule Miss Izalika October 2, at Ng Chai Hwai April 18, at 6: Unknown April 4, at 9: VirtualText of Organic Chemistry.

Presentation Description No description available. Chong Yew Lee October 1, at 7: Nur Afiza June 10, at 1: Let’s look at the questions in the previous quiz.

For woodward fieser rule having more than 4 conjugated double bonds one must use Fieser—Kuhn rules.


Thanks for the comment and sharing of another educational rhle on pharmacy and pharmaceutical chemistry. This page was last edited on 1 Juneat You woodward fieser rule not have the permission to view this presentation.

Good Molecules: Calculating UV λmax of molecules using the Woodward-Fieser Rules

Unknown February 28, at 8: I hope that this tutorial will help you. Gieser stands for a double bond outside the woodward fieser rule and Endo stands for a double bond within the ring. One set of Woodward—Fieser rules for dienes is outlined in table 1.

By using this site, you agree to the Terms of Use and Privacy Policy. Rules woodward fieser rule wavelength of maximum diene absorption [3] [7] With the aid of these rules the UV absorption maximum can be predicted, for example in these two woodward fieser rule In Fieser modified these rules with more experimental data, and the modified fiieser is known as Woodward- Feiser Rules. If the molecule contains both homoannular system and the heteroannular system.

Alkyl substituent or ring residue.